YITH WooCommerce Frequently Bought Together allows you to suggest a group of selected products on the product page to encourage users to buy more products and offer them at a discounted price also.
The integration with YITH Added to Cart Popup will let the Cart popup open automatically whenever one or more products from the Frequently Bought Together section are added to the cart.
If both plugins are installed and activated, you will be able to enable a new option on the settings page: YITH > Added to Cart Popup > General options > Enable for “Frequently Bought Together” button.

This is how the Frequently Bought Together section looks like:

If you add one or more products from the Frequently Bought Together section, the popup will open including all of them and any possible discount that had been applied:

For further details about YITH Frequently Bought Together settings, please refer to the official documentation.